![]() ![]() For more information or queries on new connections, billing, technical support, payment, or others, reach the Optimum customer service. For business establishments, Optimum has a range of voice, internet and TV packages that not only stand out for its features but also the pricing. Members also enjoy exclusive discounts on shopping, dining and travel. Register for Optimum Rewards loyalty program to enjoy discounts, access to new packages and offers. Higher medication adherence - We analyzed 3 chronic conditions participants had a 20+ higher medication adherence with home delivery 90-day vs. You can view recent bills, past payment history and even manage your services. Our research shows Optum Home Delivery reduces medication adherence barriers, drives greater health outcomes and lowers total cost of care. Payment can also be done online by logging into your account here. The stores accept cash, check, money order or credit card. Payment for bills can be done over phone or by visiting any Optimum store. Subscribers can get up to three additional Optimum Voice phone lines at their residence for a fixed fee.įor pricing and packages click here. May be a meme of 1 person, phone, telephone and text that says. Other features include anonymous call blocker, caller ID, private outbound calling, caller ID blocking, Do Not Disturb, call forwarding, enhanced voicemail, call waiting and call return. 144010 likes 3989 talking about this 327 were here. With regard to the Home Phone service, Optimum offers unlimited calling to the U.S., Canada, Puerto Rico and the U.S. For heavy WiFi users, Optimum offers Ultra 101 with download speeds of up to 101 Mbps. You’ve likely noticed that it’s the exact same phone number, although the advertised working hours are the same. Subscribers also get free smart router to set up a home wireless network. If you're experiencing issues with the service (e.g., losing internet connection or TV signal), the company prompts you to contact technical support at 88. Optimum has WiFi access at over 1 million indoor and outdoor hotspots. ![]() Weve founded our business on this connection to provide the optimum. Note that equipments such as cable boxes, HD cable box or DVR will cost additional.įor Internet subscribers, there is Ultra 50 that comes with up to 50 Mbps download speed. We understand every customer contact is an opportunity to build loyalty with your brand. If youre experiencing issues with the service (e.g., losing internet connection or TV signal), the company prompts you to contact technical support at 88. You should dial this number for general inquiries or if theres a problem with your bill. Speak to a Optimum customer service rep to schedule an appointment. The general customer service phone number is 88. of select Optimum internet plans Free standard installation when ordering online. Optimum’s Digital Cable TV offers over 165 free HD channels, movies on demand, ability to record up to 15 shows, rewind and pause live TV, free Optimum App to watch live TV on laptop, tablets and smartphones, among other features. The deals listed below include TV, Internet, and Phone service. Optimum TV, Optimum Voice, Optimum Online high-speed Internet, and Optimum WiFi are some of the popular brands offering communication services. Founded by Charles Dolan in 1973, Cablevision serves millions of residential and business customers in and around New York. PT 10 min read Provider unavailable in Starting at 40 On Altice's website Optimum home internet Rating How we calculated our rating 6.2 CNET Rating Speed 7/10 Value. Those developments that appear in bold are new additions to the Big Apple Connect program.About Optimum Optimum is a cable TV and Internet provider owned and managed by Cablevision Systems Corporation. Why am I getting a SIM is locked message on my phone See all 18 articles. Note: All developments located in Manhattan are serviced by Charter/Spectrum. Dialing Plan Change Coming to 602 & 623 Area Codes in Arizona. Those developments that appear in bold are new additions to the Big Apple Connect program. Note: Service provider for Brooklyn developments indicated in parentheses below. Optimum failed to deliver phone I bought o line phone was paid online 17 dollars was sent. ![]() Those developments that appear in bold are new additions to the Big Apple Connect program. Optimum Reviews, Complaints & Contacts Complaints Board. Get help Moving Easily transfer your service to a new address. Find a store Get the most out of your service with FAQs, tutorial videos, and more. Chat now Visit one of our retail locations. You can also get the best possible mobile customer support by interacting with them online. Contact us for general, billing, or technical support. For sales for all other regions, you can phone (844) 215-5225. Note: All Bronx developments below are serviced by Altice/Optimum. Call 1-86 Already have Optimum We’re here to help. ![]()
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![]() 3-Floor White Container House 3-Floor White Container House by ManDooMiN The two glass circles provide a lovely look into the small idyllic home from the outside, as well as allowing all that lovely natural sunlight into the home during the day. If you're after another home that blends faultlessly into the landscape, then you can use this lovely mountainside house by JUNS MAB Architecture tutorial as inspiration. Mountain-Side House Mountain-Side House by JUNS MAB Architecture And the lighting looks even better with one of the best Minecraft shaders installed - or even ray tracing, if your PC is up to the task. Even ignoring the splendid cherry blossom trees on the outskirts made from pink and white wool, this is a fabulous build filled with interesting layerings of wooden slabs and soft lighting provided by lanterns and redstone lamps. ![]() SheepGG brings us a rather different style of home this time, with an attention-grabbing and aesthetically pleasing Japanese pagoda house. Japanese Pagoda-Style House Japanese Pagoda-Style House by SheepGG The chains and lanterns, the flora creeping up the walls, the shutters made from trapdoors, and the excellent clock faces in the towers all combine to make this house a real feast for the eyes. ![]() This painstakingly crafted manor is made from logs and stone bricks, but the real strength is in the little details. If you're after inspiration for a slightly larger base, then take a look at this marvellous fantasy mansion from YouTuber BigTonyMC. Fantasy Mansion Fantasy Mansion by BigTonyMC It even has a secret room containing a Nether Portal. The central circle is for storage, and the outer areas have enough space for farmland, enchanting, sleeping, and everything else you might want to do in your home. In an attempt to create the ultimate underground house, YouTuber ItsMarloe has put together an unusual and striking clover-shaped base with a glass roof that lies flush with the ground. Larger Underground House Larger Underground House by ItsMarloe Perhaps a ladder that leads down into a more expansive storage area would be a welcome addition? 4. It's small but stylish, with plenty of room for expansion downwards if you'd like to take this design as inspiration for a slightly larger house. Simple Underground House Simple Underground House by FolliĪnother nice compact build from Folli, this Minecraft house is sunk into the ground, with stairs leading up onto the surface at each of the cardinal directions. You can thank YouTuber SheepGG for this particular build. It is made out of more traditional oak and birch wood, but the combination of fences, logs, planks, slabs, and trapdoors adds a lot of variety and texture to the build (even without the use of Minecraft texture packs), and turns the whole thing into a much more appealing starter house than most others you're likely to come across. ![]() This wooden house is a starter home worthy of even the best Minecraft seeds. Simple Wooden Survival House Simple Wooden Survival House by SheepGG It's a small, cosy, rustic house that strikes me as the perfect forward base to build far from your main home, to make life a little easier. If you want to set up home in The Wild Update's new biome, then YouTuber Folli has created a lovely looking starter house out of materials found in the biome. Mangrove Starter House Mangrove Starter House by Folli If you're after inspiration for other architectural projects besides houses, be sure to check out our list of things to build in Minecraft! We've also got dedicated guides for Minecraft tower ideas and Minecraft castle ideas. ![]() ![]() ![]() The result was as soothing as sunglasses on a summer morning. Reading news late at night on an iPad, I would frequently use the polarization setting to darken the screen, even though it turned photos into negatives, until the iPad OS itself went dark this year. In short, I detested white screens the way a vampire detests sunlight. (Apple Music started offering Dark Mode this year, a factor that certainly increases the chances of my switching.) I stuck with Spotify, and resisted Apple Music's rival streaming service, entirely because of Spotify's green-on-black theme. I switched to rival writing app Ulysses because I could customize cool blue text on a black background. My first user review on the Mac app store, in 2016, slams early Dark Mode adopter Simplenote - not for the background, but because an update had made its font too bright. Now, not to sound like a hipster goth or anything, but I was way out ahead of this trend. Puts Twitter in dark mode Puts phone in dark mode Puts soul in dark mode Ah that's better. And this seems to suit our mood just fine, as if the entire world is entering a goth phase all at once. And Instagram's Dark Mode, released in October, was probably the greatest victory for the low-light feature in 2019.Īll in all, some 92 popular apps and services now offer Dark Mode, according to this exhaustive list. By that time, Facebook was testing Dark Mode on Android by December the option had spread to WhatsApp on Android. A "secret" feature to enable Dark Mode in Messenger chats by typing a moon emoji, released in the spring, turned into fully-fledged Dark Mode in the fall. Twitter, not content with being somewhat dark (gray-blue) in 2018, went full dark in 2019.įacebook was relatively slow to get Dark Mode religion, but it is now converting quickly. Mac OS offered a la carte Dark Mode in 2018, then enabled Dark Mode across the board in its 2019 edition. ![]() ![]() Gmail, Slack, Soundcloud, the mobile version of Microsoft Office, and Google Chrome all went dark this year. Android Q did the same for the Dark Side of the mobile world (sorry not sorry, Android users). Apple's iOS 13 turned millions of iPhones dark at once. Back then, apps were just beginning to offer Dark Mode, where bright pixels were shunned in favor of a black background, supposedly easier on the eyes.įast forward to 2019 - and as the political darkness grew to impeachable proportions, the trickle of Dark Mode apps became a flood. Not just in the metaphorical sense of a global wave of authoritarianism and ignorance, but literally darker - on the screens in our pockets, bags, and on our desks. Indeed, the world did seem to want it darker. "You want it darker?" the late Leonard Cohen asked on the title track of his ominous final album, released just weeks before Trump's election in November 2016. ![]() ![]() However, I would like to go further into the actual cost of these ammo supplies and present a better comparison of their cost to power ratio. Now, I know this has likely been suggested before, and denied due to the power of the other types of ammo. Length of (the wing of) arrow head in the same unit as x-axisWith the existence of the Endless Quiver and the Endless Musket Pouch, I am suggesting that there should also be and endless ammo supply for other variants of ammo. Other parameters (e.g., 'linewidth') applicable to plot for regular plots or patch for colorful arrows. Providing this as an input variable could save some time. However, this costs a lot of time in repeating hundreds of plots with the same configuration. Note: this does not support colorful plots yet.īy default, FUN_quiver_by_plotV2 will get it by calling plotboxpos. True: The returned handles h1 & h2 are matrix (one for array body and one for arrow head) This is useful if you want to change properties of a subsample of arrows.įalse: The returned handles h1 & h2 are 1 x 1 matrix (one for array body and one for arrow head) ![]() This is for vector time series and some special cases.Ĭall plot via arrayfun. Minimal length of arrow head length in units of pixel.Ģ*head_angle is the angle between the two wings of the arrow head. 1~0: it is the percent of total vector length at each point. >0 : it is the absolute length of the arrow head (Thus, the vel_scale will also be applied to head_length)Ġ : it is set according to the gca (width & length in pixel). Length of (the wing of) arrow head in units of pixel In this case, patch, instead of plot, is used to plot arrow heads. If this is true, a filled triangle will be used as the head of each arrow. otherwise: this scale will be applied to u and v. 1: No scale, the original u/v will be used = FUN_quiver_by_plotV2( x, y, u, v, vel_scale. = FUN_quiver_by_plotV2( x, y, u, v, vel_scale) ![]() If you are in a command line environment: Then, click "Add Folder.", add the root path of this package (the folder contains functions FUN_quiver_by_plotV2*.m), then click "Save" near the bottom of the dialog. It will open a dialog for setting the path. It can be done by two ways: If you have GUI access to Matlab :Ĭlick "Home tab> Set Path". The subfolders ( private, doc) should not be added to the searching path. The private folder must be put in the same folder as FUN_quiver_by_plotV2*.m. You need to add this to the searching path of your Matlab environment before using them. To create a perfect arrow, the xlim and ylim must be defined explicitly and it should not be changed after calling this toolbox. This is similar to FUN_quiver_by_plotV2_cmap_patch but the color is defined based on a fixed colormap, which must be specified ![]() This is same as FUN_quiver_by_plotV2_cmap_patch.m but compatible with mmap This is same as FUN_quiver_by_plotV2.m but compatible with mmap The length of head (fixed length, or a ratio to the arrow length, etc.)Ĭolorful arrows adopted to current colormap The arrows are generated by plot/ patch, which provides the possibility that everything can be adjusted. More flexibility than the built-in function quiver. Introduction 1.1 Features/Why I wrote this ![]() ![]() ![]() How do you create the perfect frozen drink texture with a Margaritaville machine?Ī. The brand is named after the hit song “Margaritaville” sung by Jimmy Buffett, and the company is owned by Margaritaville Holdings LLC (a subsidiary of Cheeseburger Holding Company, LLC). Margaritaville blender FAQ Who owns Margaritaville blender?Ī. The most affordable full-featured Margaritaville Bahamas margarita machine costs about $200, but you will have to spend about $500 for the high-volume Tahiti Frozen Concoction Maker. How much you can expect to spend on a Margaritaville blender ![]() The Margaritaville Bali Frozen Concoction Maker offers pre-programmed settings to blend margaritas, daiquiris, piña coladas and smoothies in no time. Just add the ice and the ingredients for your favorite drink, select your portion setting and flip the Shave and Blend switch. Margaritaville machines offer automatic presets to help blend up a few quick drinks. The remix channel blends and dispenses each serving to achieve a smooth, restaurant-quality texture for every drink. Some of the models include an on-demand self-dispensing lever and spout that allows party guests to serve themselves by merely placing their glass underneath. Each is built with thick and sturdy glass to hold up to the rigors of blending and ice shaving. Quality reservoirsĪll Margaritaville machines include at least two reservoirs: the ice bowl and the pitcher. All that power shaves ice without difficulty or overheating. The Key West model comes with a 450-watt motor while the Bali model boasts a 650-watt electric motor. Inside the base, Margaritaville equips its machines with durable and resilient motors. The motor housing weight, balance and sure footing keep vibration to a minimum, ensure safe operation and produce relatively little noise. The premium build quality of the Margaritaville Concoction Makers begins with a robust base. What to look for in a quality Margaritaville blender Robust work base Margaritaville machines are available with 36-ounce pitchers that hold enough margarita mix for six to eight people and the larger capacity machines such as the Tahiti Frozen Concoction Maker is equipped with three 24-ounce blending jars that automatically produce 72 ounces of frozen drink per cycle. With the right measurements and presets for various drinks, anyone can make the perfect margarita or piña colada. You can leave the ingredients next to the machine and let your guests make their own drinks. The mixer also makes hosting a margarita party a breeze. Just place the mixer on the top of the margarita machine’s blender jar, fill the ingredients to the designated line and then pour them in. Measuring ounces, tablespoons or shot glasses are not required. Margaritaville machines include a no-brainer mixing tool with measurements for making margaritas, piña coladas and daiquiris. The machine shaves the ice first before blending all the ingredients. A margarita machine is both an ice shaver and blender. In a blender, all the ingredients including the ice are placed in the pitcher and a press of the button begins the blending process. Shaving and blending separatelyīlenders and margarita machines prepare drinks differently. The result is a pleasant ice-cold beverage with a classic margarita texture and taste. Shaved ice flakes feel fluffy rather than chunky and the ice melts more slowly. ![]() Even some restaurants serve margaritas with ice pieces that are too large or so small they melt immediately.Ī dedicated margarita machine, such as the Margaritaville Bahamas Frozen Concoction Maker, produces perfect granules every time because it shaves the ice instead of crushing it. A high-quality machine does it very well, but they can still leave small chunks of ice in the blend when used to make a margarita. What to know before you buy a Margaritaville blender Soft, smooth iceĪ blender is an appliance designed to crush, mix or emulsify food and other substances. Margaritaville brand machines are the best on the market and the Bali Frozen Concoction Maker model is the top choice. ![]() While a regular blender can produce a frozen margarita, a dedicated margarita maker is needed to create a restaurant-quality drink with the ideal texture. The margarita is often served on the rocks or straight up, but it becomes a delightfully refreshing tequila cocktail when served in a smooth frozen slush. The original version is a simple blend of tequila, fresh lime juice and orange liqueur, but today there are dozens of fruity variations. Which Margaritaville blender is best?Īlthough the origins of the margarita drink are unclear, many consider it to be the quintessential “Mexican” cocktail. Please look at the time stamp on the story to see when it was last updated. This is an archived article and the information in the article may be outdated. ![]() ![]() ![]() The city of Saint Denis is the biggest town to ever be included in a Red Dead Redemption game, and as such, it is truly a sight to behold. ![]() The jagged peaks and scattered glaciers, as well as deep valleys that are easy to get lost in, are the biggest giveaways of the developers' inspiration by the Rockies. The Grizzlies mountains (both East and West), are quite obviously inspired by the Rocky Mountains located in Colorado (also known as the Rockies). Is Grizzlies West Inspired By A Real-Life Location? As the only region in the game that's completely covered in snow, it makes for a pleasant change of pace and environment. Grizzlies West is worth returning to even after rescuing John Marston and leaving the area with Dutch's gang in the prologue. Luckily, it is unmissable, as Arthur Morgan's adventure starts in this part of the map, the Spider Gorge location to be precise. Home to inspiring views such as the Lake Isabella or Mount Hagen, this region of RDR2 is a must-see. Located in the state of Ambarino, the Grizzlies are a tall mountain range, characterized by very steep cliffs and passages that are almost too difficult to pass through for the unwary traveler. Suffice it to say, many players will have their personal favorites when it comes to the many amazing views in this game. The story of Arthur Morgan as he slowly gets disillusioned with Dutch's gang is a riveting experience that fans absolutely love, and it helps that the game has so many amazing vistas and beautiful locales that the simple act of exploration becomes an amazing time in its own way. Updated on June 2, 2023, by Ritwik Mitra: Red Dead Redemption 2 is one of the greatest open-world games ever made, with this title being full to the brim with everything from memorable characters to some of the greatest set-pieces Rockstar has ever devised. It's clear that the designers in Rockstar are skilled in every way, given how this vast open world is so visually distinct in every way that people will have their own favorites when it comes to the many beautiful sights present in this beautiful game. Players still tend to return to some of the most beautiful locations in Red Dead Redemption 2, just to take in the landscape and marvel at the environmental diversity of the game. RELATED: Weirdest Encounters In The Red Dead Redemption SeriesĮven now, Rockstar's masterpiece still holds up as the unofficial industry standard for high-quality graphics in games and an example of ambitious, realistic open-world design. Of course, it helped that the gameplay loops of this title were phenomenal, with the story being a notable highlight that many people consider to be Rockstar's magnum opus, and understandably so. It combined beautiful landscapes, majestic vistas, and naturally behaving wildlife to create the most immersive gaming experience in recent memory. When it was first released in 2018, Red Dead Redemption 2was hailed as one of the most beautiful games of its console generation. ![]() ![]() ![]() How Much Will SmartCore Ultra Flooring Cost?Ĭartons of Smartcore Ultra premium vinyl plank flooring are available, and they may cover an area ranging from 15 to 28 square feet.
![]() “Apparently this is the fourth fatality for a DTE work crew.” “OSHA was here yesterday,” continued Edelstein, disturbed by the dangerous conditions. The worker died in the hole where they attempted to get to the leak.” They started working on the main and it failed. In this case, the homeowner did phone because he smelled gas. He went on, “It’s older infrastructure, and the company’s position is that if there is no leak, they don’t replace it. “It appears the gas displaced the air and he ended up suffocating to death.” “My understanding is the gas main that was there failed and the DTE guy was in the ditch,” stated Edelstein. Matthew Edelstein, who lives near the accident location, told the WSWS that the problems with gas leaks in the area had been on going on for more than two weeks. They also concurred with the comment that DTE workers’ conditions were not so different from those who face utility shutoffs at the hands of the energy giant. While they could not comment, they nodded their heads in agreement when it was pointed out that this was happening all too frequently to utility workers. However, the workers said they were instructed not to talk to the media or anyone outside the company. On Wednesday this reporter approached another two-man DTE crew working in the vicinity of the accident. Paramedics removed Issac from the hole and tried to revive him, but he was pronounced dead on arrival at a local hospital. ![]() Issac’s co-worker, whose name has not been released, called 911 when he noticed his partner was slumped over and unconscious. ![]() Five-foot hole dug by different DTE crew 25 feet away from similar hole that resulted in Thomas Issac’s death ![]() ![]() ![]() Mix into cookies, pancakes, oatmeal, or coffee. Blast your favorite foods Sprinkle on toast, yogurt, ice cream, fruit, or popcorn. If you are dissatisfied with the quality of a product, please contact us within 5 days of the delivery. This crazy-delicious cinnamon blend delivers the taste you love with notes of caramel, vanilla and graham avor. Cinnamon Toast Crunch Cinnadust Seasoning. American Food Avenue will not be held responsible once your package has left our hands. Cinnamon Toast Crunch Cinnadust Seasoning found at Hannaford Supermarket. In case your package has suffered damage during transit, please notify your local post office as soon as possible and let them assess the package for you. We take great caution in packaging your goods and sending them to you. Prior to sending them to you we check that the products have not been damaged or altered in any way. Damaged Goods and RefundsĪll products that we sell have been imported directly from the USA. But we do try hard to remain competitive by providing the best pricing possible. All our prices are displayed in Swiss francs and American Food Avenue reserves the right to change these without prior notification. Whilst every effort is made to ensure the packaging, sizes and prices are accurate to specification American Food Avenue can not be held responsible for supplying goods that differ form the information given on the website. The information contained within this web site and online store are, to the best of our knowledge, correct at the time of publishing. These terms and conditions and all disclaimers and other material on our website shall be governed by and construed in accordance with Swiss law and any disputes shall be referred to the exclusive jurisdiction of the courts of the canton of Geneva. The information we collect about you is purely for the purpose of processing your order and providing you with the best possible service.The subscription on our mailing list required for the ease of the customers and they are to unsubscribe at any time. This crazy-delicious cinnamon blend delivers the taste you love with notes of caramel, vanilla and graham flavor. We will not sell, or give, or otherwise share your details with any third party. Roasted Sweet Potato Fries with Cinnadust. No materials available on this website may be stored, transmitted by any means (including but not limited to electronic, mechanical, scanning, photocopying or recording), republished or misappropriate any part of it Any misuse of the material on this website may result in legal action taken by Privacy Policy Blast your favorite foods Sprinkle on toast, yogurt, ice cream, fruit, or popcorn. By accessing the site, you accept these conditions without limitation or reservation.Īll content in this website, including the logo of the company American Food Avenue is protected by copyright. The accessing and use of this site are subject to the following conditions and the legal provisions in force. Reserve the right to amend the content of the site at any time without notice and will not be held responsible for the consequences of such amendments. ![]() ![]() ![]() Such reactions have not yet been feasible for mechanochemical investigation, even by ex situ approaches which require many individual experiments to map the evolution of a reaction profile. However, in many cases, materials are expensive or toxic. Similarly, difficulties with data collection strategies for established TRIS-XRPD methods have demanded the use of large solid loadings, typically hundreds of milligrams 13, 27. In turn, it has not been yet possible to extract the intricate mechanistic detail required to fully elucidate the mechanisms of mechanochemical transformations from TRIS data.įor instance, the determination of crystallite size which has appeared as a fundamental factor in mechanochemical transformations 32, 33, remains largely outside the scope of current TRIS capabilities. Despite the significant progress made in the study of mechanochemical reactions through TRIS-XRPD, the quality of attainable data has remained poor. TRIS-XRPD has proved especially promising for identifying unexpected and short-lived intermediates, including indications of short-lived amorphous phases 31. This has included studies on the rates and mechanisms of both chemical 29 and physical transformations 30. As mechanochemistry is predominantly a solid-state synthesis technique, TRIS-X-ray powder diffraction (XRPD) has remained a focal point for mechanochemical investigation. For example, TRIS Raman spectroscopy 26, 27 has allowed unrivalled insight into the rates and mechanisms of ball milling covalent organic chemical reactions and solid–solvent interactions 26, while advances in TRIS X-ray spectroscopy have allowed the study of redox chemistry during nanoparticle mechanosynthesis 28. Time-resolved in situ (TRIS) monitoring approaches have opened the door to exceptional detail regarding mechanochemical reactions 13. Such reactions can be only studied by directly probing the reaction in situ during mechanical treatment. Moreover, examples are known where the stop-start ex situ approach causes the system to evolve via a pathway alternative to the unperturbed reaction 24, 25. However, many systems continue to transform even after milling is stopped 22, 23. Where reaction products are long-lived, ex situ methods provide a powerful means to investigate mechanochemical mechanisms. Traditionally, mechanochemical reactions have been studied ex situ, wherein the reaction is stopped and material is removed from the reactor for analysis. This lack in understanding and control represents a significant barrier to realising the full potential of this world-changing technology. Despite decades of research 21, the fundamental principles which drive mechanochemical reactions remain poorly understood. Providing “greener” and potentially less-expensive strategies than traditional solution methods 1, 17, 18, 19, mechanochemistry was dubbed by the International Union for Pure and Applied Chemistry (IUPAC) as one of the 10 chemical innovations that will change our world 20. It is increasingly clear that many traditional solution-based chemical reactions can be performed in the presence of very little or no solvent using mechanochemical approaches 16. Mechanochemistry has emerged as an attractive and sustainable synthetic tool 1, 2 with applications for the synthesis of organic 3, 4, 5, 6, 7, inorganic 8, 9, 10, 11 and hybrid metal-organic molecules and materials 12, 13, 14, 15. Our strategy is applied to model systems, including inorganic, metal-organic, and organic mechanosyntheses, resolves previously misinterpreted mechanisms in mechanochemical syntheses, and promises broad, new directions for mechanochemical research. This offers a direct avenue towards the mechanochemical investigation of reactions comprising scarce, expensive, or toxic compounds. This strategy applies to all chemistries, is readily implemented, and yields high-quality diffraction data even using a low energy synchrotron source. Moreover, microstructural parameters (crystal size and microstrain) can be also determined with high confidence. Accurate phase compositions, comparable to those obtained by ex situ measurements, can be obtained with small sample loadings. Here we report how a combination of miniaturised grinding jars together with innovations in X-ray powder diffraction data collection and state-of-the-art analysis strategies transform the power of TRIS synchrotron mechanochemical experiments. Time resolved in situ (TRIS) monitoring has revolutionised the study of mechanochemical transformations but has been limited by available data quality. ![]() |
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